| DOI | Trouver le DOI : https://doi.org/10.1007/s00216-009-2619-x |
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| Auteur | Rechercher : Meija, Juris1Identifiant ORCID : https://orcid.org/0000-0002-3349-5535; Rechercher : Ouerdane, Laurent1; Rechercher : Mester, Zoltán1Identifiant ORCID : https://orcid.org/0000-0002-2377-2615 |
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| Affiliation | - Conseil national de recherches du Canada. Institut des étalons nationaux de mesure du CNRC
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| Format | Texte, Article |
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| Sujet | isotope dilution; multiple spiking; uncertainty; error propagation; Monte Carlo; isotope scrambling |
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| Résumé | The purpose of performing multiple spiking isotope dilution is to quantify interconverting substances. This feature has been utilized in analytical chemistry now for more than a decade. In this manuscript we show that the interconversion of analytes is inevitably accompanied by the gradual loss of information that can be extracted from the isotope patterns. Therefore, any corrections for analyte interconversion are performed at the expense of the precision of the obtained amount of interconverting analytes. Consequently, there is a natural, predictable limit to the applicability of multiple-spiking isotope dilution methods that can be summarized into a simple equation. |
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| Date de publication | 2009-02-10 |
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| Maison d’édition | Springer |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 23001628 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | f1e1136e-df46-479e-9368-d40c3efcae20 |
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| Enregistrement créé | 2017-03-13 |
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| Enregistrement modifié | 2020-04-16 |
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