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Comparison of sample digestion techniques for the determination of trace and residual catalyst metal content in single-wall carbon nanotubes by inductively coupled plasma mass spectrometry

Par Conseil national de recherches du Canada

DOITrouver le DOI : https://doi.org/10.1016/j.sab.2014.09.009
AuteurRechercher : 1; Rechercher : 1; Rechercher : 2; Rechercher : 1; Rechercher :
Affiliation
  1. Conseil national de recherches du Canada. Science des mesures et étalons
  2. Conseil national de recherches du Canada
FormatTexte, Article
SujetActivation analysis; Carbides; Carbon nanotubes; Catalysts; Inductively coupled plasma mass spectrometry; Isotopes; Laser ablation; Lead; Mass spectrometers; Mass spectrometry; Mercury (metal); Molybdenum; Neutron activation analysis; Nickel; Trace analysis; Trace elements; ICP-MS; Metal content determination; Microwave-assisted acid digestion; Microwave-induced combustion; Ni and co catalysts; SWCNT; Trace metal impurities; Single-walled carbon nanotubes (SWCN)
Résumé
A single-wall carbon nanotube material produced by laser ablation of renewable biochar in the presence of Ni and Co catalyst was characterized for residual catalyst (Co and Ni) as well as trace metal impurity content (Fe, Mo, Cr, Pb and Hg) by isotope dilution ICP-MS following sample digestion. Several matrix destruction procedures were evaluated, including a multi-step microwave-assisted acid digestion, dry ashing at 450 C and microwave-induced combustion with oxygen. Results were benchmarked against those derived from neutron activation analysis and also supported by solid sampling continuum source GF-AAS for several of the elements. Although laborious to execute, the multi-step microwave-assisted acid digestion proved to be most reliable for recovery of the majority of the analytes, although content of Cr remained biased low for each approach, likely due to its presence as refractory carbide.
Date de publication
Dans
  • Spectrochimica Acta - Part B Atomic Spectroscopy 105, nº 1 March 2015 (18 octobre 2014) : 89–94.
Langueanglais
Publications évaluées par des pairsOui
Numéro NPARC21275746
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Identificateur de l’enregistrementce3a46cd-6285-45d6-bb07-a1cff8b7e97a
Enregistrement créé2015-07-14
Enregistrement modifié2020-04-22
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