| Téléchargement | - Voir le manuscrit accepté : Reducing the matrix effects in chemical analysis: fusion of isotope dilution and standard addition methods (PDF, 779 Kio)
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| DOI | Trouver le DOI : https://doi.org/10.1088/0026-1394/53/2/829 |
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| Auteur | Rechercher : Pagliano, Enea1; Rechercher : Meija, Juris1Identifiant ORCID : https://orcid.org/0000-0002-3349-5535 |
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| Affiliation | - Conseil national de recherches du Canada. Science des mesures et étalons
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| Format | Texte, Article |
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| Résumé | The combination of isotope dilution and mass spectrometry has become an ubiquitous tool of chemical analysis. Often perceived as one of the most accurate methods of chemical analysis, it is not without shortcomings. Current isotope dilution equations are not capable of fully addressing one of the key problems encountered in chemical analysis: the possible effect of sample matrix on measured isotope ratios. The method of standard addition does compensate for the effect of sample matrix by making sure that all measured solutions have identical composition. While it is impossible to attain such condition in traditional isotope dilution, we present equations which allow for matrix-matching between all measured solutions by fusion of isotope dilution and standard addition methods. |
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| Date de publication | 2016-02-15 |
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| Maison d’édition | IOP Publishing |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 21277305 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | 751ca88d-3e64-43f6-96e8-37a479b9c7c5 |
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| Enregistrement créé | 2016-02-24 |
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| Enregistrement modifié | 2020-06-04 |
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