| DOI | Resolve DOI: https://doi.org/10.1039/P29820000751 |
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| Author | Search for: Kennedy, A.J.; Search for: Walton, J.C.; Search for: Ingold, K. U.1 |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Abstract | Spiropentyl radical was generated by hydrogen abstraction from spiropentane by t-butoxyl radical and its e.s.r. spectrum obtained. The experimental e.s.r. parameters were compared with computational results obtained using semi-empirical SCF MO methods. The spiropentyl radicals do not undergo β-scission in the observable temperature range (T < 380 K). The main process in the halogenation of spiropentane at 293 K in CCl4 solution involves SH2 attack by the halogen atom to give 1-(halogenomethyl) cyclopropylmethyl radicals. The β-scission of these latter radicals has been investigated by e.s.r. spectroscopy and by the reduction of 1,1-bisbromomethyl-cyclopropane with tri-n-butyltin hydride. |
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| Publication date | 1982 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21276706 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | c4914e06-3b0a-4cc3-ba30-627df181f4c4 |
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| Record created | 2015-10-13 |
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| Record modified | 2020-03-13 |
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