| DOI | Trouver le DOI : https://doi.org/10.1021/cm0497529S0897-4756(04)09752-2 |
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| Auteur | Rechercher : Xu, Z.; Rechercher : Braterman, P.; Rechercher : Yu, Kui1; Rechercher : Xu, H. (Hongyi)2; Rechercher : Wang, Y.; Rechercher : Brinker, C. |
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| Affiliation | - Conseil national de recherches du Canada. Institut Steacie des sciences moléculaires du CNRC
- Conseil national de recherches du Canada. Institut de recherche aérospatiale du CNRC
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| Format | Texte, Article |
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| Résumé | We report a novel packing mode specific to the cis unsaturated hydrocarbon chain in the title compound, a self-assembled layered double hydroxide-surfactant hybrid nanomaterial, and its influence on crystallite morphology and structure. The kink imposed by the cis double bond in oleate leads to partial overlap between chains on adjacent layers, with incomplete space filling, in contrast to the more usual (and more efficient) mono- and bilayer packings exhibited by the trans analogues. Incorporation of surfactant into the growing crystallite leads to a reversal of the usual LDH growth habit and results in crystallite shapes featuring ribbonlike sheets. The thermal decomposition behavior of the as-prepared organic/inorganic nanocomposites in air and N2 is described. |
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| Date de publication | 2004-07-13 |
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| Dans | |
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| Numéro NPARC | 12339244 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | d6e46895-f635-46a5-bd2e-e6708b65ad48 |
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| Enregistrement créé | 2009-09-11 |
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| Enregistrement modifié | 2020-04-17 |
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