| Téléchargement | - Voir le manuscrit accepté : Hosting various guests including fullerenes and free radicals in versatile organic paramagnetic bTbk open frameworks (PDF, 1.2 Mio)
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| DOI | Trouver le DOI : https://doi.org/10.1021/cg401097e |
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| Auteur | Rechercher : Bardelang, David; Rechercher : Giorgi, Michel; Rechercher : Hornebecq, Virginie; Rechercher : Stepanov, Anatoli; Rechercher : Hardy, Micael; Rechercher : Rizzato, Egon; Rechercher : Monnier, Valerie; Rechercher : Zaman, Md. Badruz; Rechercher : Chan, Gordon1; Rechercher : Udachin, Konstantin2; Rechercher : Enright, Gary3; Rechercher : Tordo, Paul; Rechercher : Ouari, Olivier |
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| Affiliation | - Conseil national de recherches du Canada. Construction
- Conseil national de recherches du Canada
- Conseil national de recherches du Canada. Technologies de sécurité et de rupture
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| Format | Texte, Article |
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| Sujet | Building blockes; Fullerene soot; Nanostructured assembly; Open frameworks; Single crystal x-ray diffraction; Free radicals; Fullerenes; X ray diffraction; Paramagnetism |
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| Résumé | The dinitroxide bis(TEMPO) bisketal (bTbk) was shown to crystallize into open frameworks whose structures were determined by single-crystal X-ray diffraction. We show that bTbk can be used as a supramolecular building block for the hosting of a plethora of guests inside the 1D channels of its paramagnetic framework, including other radicals such as TEMPO or 2-azaadamantane-N-oxyl. C60 and C70 were also found to be easily included in this open framework during its crystallization. This resulted in well-defined, nanostructured assemblies of composite radical crystals (bTbk/toluene/C60 or C70) or (bTbk/toluene/TEMPO) by a very simple dissolution/crystallization process with tunable guest content. Selective C60 extraction was also demonstrated directly from fullerene soot. |
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| Date de publication | 2014-12-10 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 21272823 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | cf28f67c-dbdb-4e1a-81c2-e598cccae9bc |
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| Enregistrement créé | 2014-12-03 |
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| Enregistrement modifié | 2020-06-04 |
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