| DOI | Trouver le DOI : https://doi.org/10.1002/aic.11844 |
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| Auteur | Rechercher : Kumar, Rajnish1; Rechercher : Englezos, Peter; Rechercher : Moudrakovski, Igor1; Rechercher : Ripmeester, John A.1 |
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| Affiliation | - Conseil national de recherches du Canada. Institut Steacie des sciences moléculaires du CNRC
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| Format | Texte, Article |
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| Sujet | gas hydrates; ice powder; spectroscopic; powder x-ray diffraction; crystal structure; H2 enclathration |
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| Résumé | Gas hydrates from a (40/60 mol %) CO2/H2 mixture, and from a (38.2/59.2/2.6 mol %) CO2/H2/C3H8 mixture, were synthesized using ice powder. The gas uptake curves were determined from pressure drop measurements and samples were analyzed using spectroscopic techniques to identify the structure and determine the cage occupancies. Powder X-ray diffraction (PXRD) analysis at −110°C was used to determine the crystal structure. From the PXRD measurement it was found that the CO2/H2 hydrate is structure I and shows a self-preservation behavior similar to that of CO2 hydrate. The ternary gas mixture was found to form pure structure II hydrate at 3.8 MPa. We have applied attenuated total reflection infrared spectroscopic analysis to measure the CO2 distribution over the large and small cavities. 1H MAS NMR and Raman were used to follow H2 enclathration in the small cages of structure I, as well as structure II hydrate. |
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| Date de publication | 2009-05-01 |
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| Dans | |
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| Langue | anglais |
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| Publications évaluées par des pairs | Oui |
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| Numéro NPARC | 16380393 |
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| Exporter la notice | Exporter en format RIS |
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| Signaler une correction | Signaler une correction (s'ouvre dans un nouvel onglet) |
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| Identificateur de l’enregistrement | c0da926e-983c-4c05-8842-5866614859bf |
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| Enregistrement créé | 2011-02-14 |
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| Enregistrement modifié | 2020-04-16 |
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