DOI | Resolve DOI: https://doi.org/10.1139/v92-038 |
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Author | Search for: Johnston, L. J.1; Search for: Wong, D. F.1 |
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Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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Format | Text, Article |
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Subject | carbocations, triplets, electron transfer, laser flash photolysis |
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Abstract | The triplet excited state of the 9-phenylxanthenium cation has been observed directly by both luminescence and transient absorption techniques. The triplet–triplet absorption shows λmax ≤ 300 nm and decays over a period of several microseconds in the absence of easily oxidized donors. The triplet cation reacts with 9-phenylxanthydrol and biphenyl via electron transfer to give the corresponding radical and radical cation and also reacts rapidly with both oxygen and 1,3-cyclohexadiene. |
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Publication date | 1992 |
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In | |
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Language | English |
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NRC number | NRCC 33253 |
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NPARC number | 12327927 |
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Export citation | Export as RIS |
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Report a correction | Report a correction (opens in a new tab) |
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Record identifier | eb0ce665-d2bd-4158-99b6-90f9c59acb86 |
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Record created | 2009-09-10 |
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Record modified | 2020-04-23 |
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