Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1021/jo400535u
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Affiliation
  1. National Research Council of Canada. National Institute for Nanotechnology
FormatText, Article
SubjectHydrogen abstraction reaction; Hydrogen bond interaction; Intramolecular hydrogen; N ,N-Dimethylacetamide; N ,N-Dimethylformamide; Rate-limiting formation; Theoretical investigations; Time-resolved kinetic study; Amides; Functional groups; Hydrogen bonds; Organic solvents; Substrates; Abstracting; acetic acid derivative; aliphatic amine; amide; benzyloxyl radical; carbon; cumyloxyl radical; dimethyl sulfoxide; hydrogen; hydroxyl radical; n,n dimethylacetamide; n,n dimethylformamide; oxygen; tertiary amine; unclassified drug; calculation; chemical reaction kinetics; chemical structure; density functional theory; dissociation constant; enzyme specificity; hydrogen bond; mathematical computing; molecular interaction; phase transition; stereochemistry
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LanguageEnglish
Peer reviewedYes
NPARC number21269778
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Record created2013-12-13
Record modified2020-04-22
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