Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding
Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding
DOI | Resolve DOI: https://doi.org/10.1021/jo400535u |
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Author | Search for: ; Search for: ; Search for: 1; Search for: |
Affiliation |
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Format | Text, Article |
Subject | Hydrogen abstraction reaction; Hydrogen bond interaction; Intramolecular hydrogen; N ,N-Dimethylacetamide; N ,N-Dimethylformamide; Rate-limiting formation; Theoretical investigations; Time-resolved kinetic study; Amides; Functional groups; Hydrogen bonds; Organic solvents; Substrates; Abstracting; acetic acid derivative; aliphatic amine; amide; benzyloxyl radical; carbon; cumyloxyl radical; dimethyl sulfoxide; hydrogen; hydroxyl radical; n,n dimethylacetamide; n,n dimethylformamide; oxygen; tertiary amine; unclassified drug; calculation; chemical reaction kinetics; chemical structure; density functional theory; dissociation constant; enzyme specificity; hydrogen bond; mathematical computing; molecular interaction; phase transition; stereochemistry |
Abstract | |
Publication date | 2013 |
In | |
Language | English |
Peer reviewed | Yes |
NPARC number | 21269778 |
Export citation | Export as RIS |
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Record identifier | e9fe8d3f-7635-41cb-921e-9cd360c3570c |
Record created | 2013-12-13 |
Record modified | 2020-04-22 |
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