| DOI | Resolve DOI: https://doi.org/10.1021/jz301954t |
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| Author | Search for: Xu, Jun; Search for: Terskikh, Victor V.1; Search for: Huang, Yining |
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| Affiliation | - National Research Council of Canada. Measurement Science and Standards
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| Format | Text, Article |
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| Subject | Adsorption ability; Adsorption capability; Adsorptive properties; Desolvation; Direct interactions; Guest molecules; Guest species; Host guest interactions; Local environments; Metal centers; Metal organic framework; Natural abundance; Powder XRD; Sensitive probe; Solid state NMR; Solvent molecules; Ultra-high magnetic fields; XRD; Adsorption; Crystalline materials; Java programming language; Solid state physics; Nuclear magnetic resonance spectroscopy |
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| Abstract | Metal-organic frameworks (MOFs) have excellent adsorption capability. To understand their adsorptive properties requires detailed information on the host-guest interaction. The information on MOF desolvation (or activation) is also crucial because the very first step of many applications requires removal of the solvent molecules occluded inside of the pores. Unfortunately, such information is not always available from powder XRD data. Solid-state NMR is an excellent complementary technique to XRD. CPO-27-Mg is a MOF with unusual adsorption ability. The adsorption involves a direct interaction between Mg and guest species. Herein, we present, for the first time, a natural abundance 25Mg solid-state NMR study of CPO-27-Mg at an ultrahigh magnetic field of 21.1 T. The results provide new physical insights into the effects of dehydration/rehydration and adsorption of guest species on the Mg local environment. |
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| Publication date | 2012-12-07 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21269842 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | e47632d0-f50a-40fe-9d64-8113b2b19323 |
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| Record created | 2013-12-13 |
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| Record modified | 2020-04-21 |
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