| DOI | Resolve DOI: https://doi.org/10.1139/V10-113 |
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| Author | Search for: Pitters, J.L.1; Search for: Adkinson, D.K.; Search for: Griffiths, K.; Search for: Norton, P.R.; Search for: Workentin, M.S. |
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| Affiliation | - National Research Council of Canada. National Institute for Nanotechnology
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| Format | Text, Article |
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| Subject | Carbenes; Diazoester; Ketene; Photochemistry; Pt surfaces; Saturated monolayers; Electron energy levels; Monolayers; Photolysis; Platinum; Single crystal surfaces; Surface reactions; Organic compounds |
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| Abstract | Irradiation of saturated monolayers of 3-and 4-substituted pyridyl diazoacetates on single-crystal Pt surfaces leads to either the corresponding reactive carbene or stable ketene intermediate with the chemoselectivity determined by the position of the photoreactive substituent on the pyridyl ring, which ultimately directs the available interactions with neighboring substrates. |
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| Publication date | 2011 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21271497 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | cb7b1643-00f8-45b5-9c59-3d4c43560785 |
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| Record created | 2014-03-24 |
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| Record modified | 2020-04-21 |
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