Download | - View accepted manuscript: Is the oxygen ‘side-On’, or ‘end-On’ and fluctional, in peroxyl radicals with magnetically equivalent oxygen atoms? (PDF, 586 KiB)
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DOI | Resolve DOI: https://doi.org/10.1139/V10-071 |
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Author | Search for: Ingold, K.U.1; Search for: DiLabio, G.A.2 |
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Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
- National Research Council of Canada. National Institute for Nanotechnology
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Format | Text, Article |
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Subject | electron paramagnetic resonance spectroscopy; density-functional theory; group-14 peroxyl radicals |
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Abstract | The g values that have been measured for the group-14 peroxyls are sufficiently similar to suggest that they all have very similar structures. However, the 17O hyperfine splittings seem to indicate that tin peroxyls have structures that differ from their lighter group-14 analogs. We hypothesize that the oxygen atoms in tin peroxyls are magnetically equivalent because they undergo a rapid 1,2-shift. Density-functional and wave-function theory calculations support this view. |
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Publication date | 2010-01-01 |
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In | |
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Language | English |
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Peer reviewed | Yes |
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NPARC number | 17653052 |
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Export citation | Export as RIS |
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Report a correction | Report a correction (opens in a new tab) |
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Record identifier | c9863aad-e82c-42b7-ad27-c29fd7354d2f |
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Record created | 2011-03-31 |
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Record modified | 2020-04-17 |
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