Radical thermochemistry and organic reactions

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Proceedings titlePure & Applied Chemistry
ConferenceNinth International Conference on Physical Organic Chemistry, 21-26 August 1988, Regensburg, Federal Republic of Germany
Pages717724; # of pages: 8
AbstractMost free radicals are transient species and it is therefore difficult to measure their thermochemical properties. We have used two new techniques that address this problem. Photoacoustic calorimetry was used to measureheats of formation of free radicals and thus homolytic bond strengths, while photomodulated voltammetry was used to measure their oxidation and reduction potentials. The data offer fresh insights into the thermochemistry of free radical processes and can therefore be used to design new reactions.
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AffiliationNational Research Council Canada; NRC Institute for Chemical Process and Environmental Technology
Peer reviewedNo
NPARC number12328294
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Record identifierc0240d37-2673-4482-b2d8-346ff41f778b
Record created2009-09-10
Record modified2016-05-09
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