Water-fluorine chains in (n-Bu)₄NF·5.5H₂O hydrate

  1. Get@NRC: Water-fluorine chains in (n-Bu)₄NF·5.5H₂O hydrate (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1016/S1472-7862(03)00056-X
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Journal titleJournal of Supramolecular Chemistry
Pages449451; # of pages: 3
SubjectAlkylammonium; Clathrate hydrate; X-ray structure
AbstractThe structure and composition of (n-Bu)4NF?5.5H2O hydrate were determined from single crystal X-ray diffraction data at 173 K. It is monoclinic C2/c with cell parameters a=16.590(3), b=17.040(3), c=16.510(3) Å, β=103.18(3)°. Water molecules and fluorine ions connected by hydrogen bonds form cages consisting of two square faces and four pentagonal faces. These cavities are connected to each other, forming an infinite chain parallel to the c axis of the crystal.
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AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
NPARC number12328032
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Record identifierafb70bdf-afcd-413f-8499-82f193d9b9c9
Record created2009-09-10
Record modified2016-05-09
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