Suspension Plasma Spraying of Nanostructured WC-12 Co Coatings

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Proceedings titleBuilding on 100 years of Success : Proceedings of the 2006 International Spray Conference
ConferenceInternational Thermal Spray Conference 2006 (ITSC 2006), Seattle, Washington, May 15-18, 2006
Subjectnanostructured coatings; suspension plasma spraying; tugsten-carbide cobalt
AbstractNanostructured WC-12% Co coatings were deposited by suspension plasma spraying of submicron feedstock powders, using an internal injection plasma torch. The liquid carrier used in this approach allows for controlled injection of much finer particles than in conventional thermal spraying, leading to thin coatings with a fine surface finish.Apolyethylene-imine (PEI) dispersant was used to stabilize the colloidal suspension in an ethanol carrier. In-flight particle states were measured for a number of operating conditions of varying plasma gas flow rates, feed rates, and standoff distances and were related to the resulting microstructure, phase composition (EDS, SEM, XRD), and Vickers hardness. High in-flight particle velocities (>800 m/s) were generated, leading to dense coatings. It was observed that the coating quality was generally compromised by the high temperature and reactivity of the small particles. To compensate for this shortcoming, the suspension feed rate was adjusted, thereby varying the thermal load on the plasma. Results showed that a slightly larger agglomerate size, in conjunction with low particle jet temperatures, could somewhat limit the decomposition of WC into brittle W₂C/W₃C and amorphous cobalt containing binder phases.
Publication date
PublisherASM International
AffiliationNational Research Council Canada (NRC-CNRC); NRC Industrial Materials Institute
Peer reviewedNo
NRC number53712
NPARC number15884102
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Record identifieraa67a9ce-dad9-44ce-803e-03f8c0784d69
Record created2010-07-30
Record modified2016-05-09
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