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Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes: formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2-P(NiPr2)=NR}] and diazoalkane insertions into metal–phosphorus bonds

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1039/b505472a
AuthorSearch for: 1; Search for: 1; Search for: 1
Affiliation
  1. National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
FormatText, Article
Abstract
The bridging phosphinidene complexes [Mn2(CO)8(μ-PNiPr2)] and [Co2(CO)4(μ-dppm)( μ-PNR2)] (NR2 = NiPr2, TMP) react with heterocumulenes RN3, CH2N2 and Ph2C[double bond, length as m-dash]N[double bond, length as m-dash]N to form complexes with μ-η1,η2-aminophosphaimine, μ-η1,η2-aminophosphaalkene and μ-η1,η2-aminophosphadiphenylmethylazaimine ligands, respectively.
Publication date
In
  • Chemical Communications, no. 35 (2005): 4441–4443.
LanguageEnglish
NPARC number12338550
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Record identifier9fcf2a4b-e3cd-41ff-868d-601abf83cd90
Record created2009-09-10
Record modified2020-04-07
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