Download | - View accepted manuscript: Isomerization of Triphenylmethoxyl: The Wieland Free-Radical Rearrangement Revisited a Century Later (PDF, 589 KiB)
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DOI | Resolve DOI: https://doi.org/10.1002/anie.201001008 |
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Author | Search for: DiLabio, Gino A.1; Search for: Ingold, K. U.2; Search for: Lin, Shuqiong2; Search for: Litwinienko, Grzegorz; Search for: Mozenson, Olga2; Search for: Mulder, Peter; Search for: Tidwell, Thomas T. |
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Affiliation | - National Research Council of Canada. National Institute for Nanotechnology
- National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
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Format | Text, Article |
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Subject | peroxide; radical reactions; reaction kinetics; rearrangements |
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Abstract | Old wisdom teaches a new lesson: The rate constant for the isomerization of thermally generated triphenylmethoxyl to Ph2(PhO)C. has been determined both experimentally and by DFT calculations (see scheme), and the results vindicated Wieland's 1911 observations and conclusions—in contrast to photochemically based findings. |
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Publication date | 2010-01-01 |
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In | |
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Language | English |
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Peer reviewed | Yes |
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NPARC number | 17653055 |
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Export citation | Export as RIS |
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Report a correction | Report a correction (opens in a new tab) |
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Record identifier | 95accc0f-9874-4b32-82c6-ba220d0c190d |
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Record created | 2011-03-31 |
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Record modified | 2020-04-17 |
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