| DOI | Resolve DOI: https://doi.org/10.1021/ja900306m |
|---|
| Author | Search for: Bardelang, David; Search for: Banaszak, Karol; Search for: Karoui, Hakim; Search for: Rockenbauer, Antal; Search for: Waite, Melanie1; Search for: Udachin, Konstantin; Search for: Ripmeester, John A.1; Search for: Ratcliffe, Christopher I.; Search for: Ouari, Olivier; Search for: Tordo, Paul |
|---|
| Affiliation | - National Research Council of Canada. NRC Steacie Institute for Molecular Sciences
|
|---|
| Format | Text, Article |
|---|
| Subject | nitroxide; probing cucurbit; spectroscopy; single-crystal; supramolecular |
|---|
| Abstract | Nitroxide free radicals are demonstrated to be useful guests for probing cucurbit[n]uril (CB[n]) assemblies in water by EPR spectroscopy. CB[7] and CB[8] significantly aggregate either in solution or in the solid state (as evidenced by a single-crystal X-ray structure in which CB[8] forms supramolecular triangles with 4-methoxy-TEMPO). The included nitroxides show a striking resistance to biologically relevant reduction, benefiting from the carcerand effect of CB[7] and CB[8] solutions. |
|---|
| Publication date | 2009-04-01 |
|---|
| In | |
|---|
| Language | English |
|---|
| Peer reviewed | Yes |
|---|
| NPARC number | 16390066 |
|---|
| Export citation | Export as RIS |
|---|
| Report a correction | Report a correction (opens in a new tab) |
|---|
| Record identifier | 7721e657-170d-4d40-a099-2badfd453895 |
|---|
| Record created | 2011-02-14 |
|---|
| Record modified | 2020-04-16 |
|---|
