Thermodynamic properties of the Na-Bi-Pb system

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Journal titleCanadian Journal of Chemistry
Pages369371; # of pages: 3
SubjectChemistry; Concrete
AbstractThermodynamic properties of Na in an equimolar Bi?Pb alloy were determined at 723 K for compositions of 0.0075 = XNa = 0.1000 from electromotive force measurements on Na metal concentration cells with a solid Na?ß-Al2O3 electrolyte. A coulometric titration technique was used to electrochemically generate the Na metal in the Bi?Pb alloy. The results indicate that, as Na is added to Bi?Pb, the liquid becomes more associated and suggests complex species formation with an ionic character intermediate between those observed for the constituent binaries.
Publication date
AffiliationNRC Institute for Research in Construction; National Research Council Canada
Peer reviewedYes
NRC number36921
NPARC number20330681
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Record identifier74c348d4-0783-4611-ba58-925c2b8ca471
Record created2012-07-18
Record modified2016-05-09
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