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Thermodynamic properties of the Na-Bi-Pb system

From National Research Council Canada

DOIResolve DOI: https://doi.org/10.1139/v94-057
AuthorSearch for: 1
Affiliation
  1. National Research Council of Canada. NRC Institute for Research in Construction
FormatText, Article
Subjectchemistry; Concrete
Abstract
Thermodynamic properties of Na in an equimolar Bi-Pb alloy were determined at 723 K for compositions of 0.0075 = XNa = 0.1000 from electromotive force measurements on Na metal concentration cells with a solid Na?ß-Al2O3 electrolyte. A coulometric titration technique was used to electrochemically generate the Na metal in the Bi-Pb alloy. The results indicate that, as Na is added to Bi-Pb, the liquid becomes more associated and suggests complex species formation with an ionic character intermediate between those observed for the constituent binaries.
Publication date
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  • Canadian Journal of Chemistry 72, no. 2: 369–371.
LanguageEnglish
Peer reviewedYes
IdentifierIRC-P-3467
NRC numberNRCC 36921
NRC-IRC-4843
NPARC number20330681
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Record identifier74c348d4-0783-4611-ba58-925c2b8ca471
Record created2012-07-18
Record modified2020-04-27
Date modified: