| DOI | Resolve DOI: https://doi.org/10.1155/2012/463748 |
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| Author | Search for: Abou-Dakka, M.1 |
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| Affiliation | - National Research Council of Canada. Measurement Science and Standards
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| Format | Text, Article |
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| Subject | Aging time; DC field; Double layers; Interaction zone; Material interfaces; Nano-fillers; Nanofiller; Natural clays; Optimal concentration; Organoclays; Percolation thresholds; Synthetic clays; Total charge; Interfaces (materials); Polypropylenes; Thermoplastics |
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| Abstract | The evolution of the space charge and conductivity with DC poling of two types of polypropylene-(PP-) based nanocomposites (PNCs) was investigated. The PNCs were manufactured with different concentrations of synthetic and natural organoclays. The optimal concentrations of nanofiller that can efficiently mitigate the space charge with DC aging time were 2-wt% for PP-natural-clay and between 2 and 4 wt% for the PP-synthetic-clay. Above these percentages charge transport through overlapping of nanoparticles can occur due to the interaction zone of double layers formed at the nanoparticle/host material interfaces. Under DC field the overlapping increases the conductivity of PNCs and minimizes the benefit of incorporating nanofillers into PP. The total charge stored in unfilled PP increased continuously with time reaching a maximum around 5000 h before decreasing but it also changed slightly in all filled specimens. It was perceived that the smaller the size of nanofiller platelets the more efficient the charge mitigation. The conductivity of specimens containing 6 wt% of natural clay and 8 wt% of synthetic clay reached ≈6 times the level of the unfilled PP. This observation could be related and due to the crossing of the percolation threshold for these composites. © 2012 Mahmoud Abou-Dakka. |
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| Publication date | 2012 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21269530 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 572d0b4b-eda0-4342-9192-d820714ba091 |
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| Record created | 2013-12-12 |
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| Record modified | 2020-04-21 |
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