| DOI | Resolve DOI: https://doi.org/10.1021/jp408073d |
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| Author | Search for: Matsika, S.; Search for: Spanner, M.1; Search for: Kotur, M.; Search for: Weinacht, T.C. |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Subject | Central wavelength; Deep ultraviolet; Dissociative ionization; High-level ab initio calculations; Relaxation dynamics; State of the art; Strong field ionization; Ultrafast relaxation dynamics; Aromatic compounds; Dissociation; Ionization |
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| Abstract | We study the ultrafast relaxation dynamics of uracil excited to the first bright ππ* state (S2) by an ultrafast laser pulse in the deep ultraviolet (central wavelength λ0 = 260 nm). With a unique combination of strong field dissociative ionization measurements, state of the art strong field ionization calculations, and high level ab initio calculations of excited neutral and ionic states at critical points along the neutral potentials, we are able to gain a detailed picture of the relaxation dynamics of the molecule, which resolves earlier disagreements regarding measurements and calculations of the relaxation. © 2013 American Chemical Society. |
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| Publication date | 2013 |
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| In | |
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| Language | English |
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| Peer reviewed | Yes |
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| NPARC number | 21270925 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 4bdc4221-5e86-4408-b1b9-b7b497212163 |
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| Record created | 2014-02-18 |
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| Record modified | 2020-04-22 |
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