Bis(trifluoromethyl)aminyl and bis(trifluoromethyl) nitroxide

  1. Get@NRC: Bis(trifluoromethyl)aminyl and bis(trifluoromethyl) nitroxide (Opens in a new window)
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Journal titleThe Journal of Physical Chemistry
Pages35973599; # of pages: 3
AbstractThe EPR parameters for (CF3)2N· have been determined to be g = 2.00374, aN = 13.84 G, and aF = 13.84 G in CF2Cl2 from 150 to 220 K. The (CF3)2NO· radical has been generated from (CF3)2Ṅ by using isotopically enriched 17O2. It has a17O equal to 23.6 G which is higher than a17O values found for dialkyl nitroxides (19-20 G). This serves to confirm that (CF3)2NO· has a higher spin density on oxygen than other nitroxides. © 1980 American Chemical Society.
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AffiliationNational Research Council Canada (NRC-CNRC)
Peer reviewedYes
NPARC number21276517
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Record identifier3f99a8df-e250-4169-ac1d-444b8def2fd7
Record created2015-10-13
Record modified2017-03-23
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