| DOI | Resolve DOI: https://doi.org/10.1016/0020-0891(84)90067-8 |
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| Author | Search for: Rowell, N. L.1; Search for: Lockwood, D. J.1 |
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| Affiliation | - National Research Council of Canada
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| Format | Text, Article |
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| Abstract | From a temperature-dependent study of the IR absorption spectrum of crystals of cubic KZn1−xCoxF3 (with 0 < x < 0.15) we have identified electronic and vibronic transitions associated with isolated clusters of Co2+ ions. Single-ion transitions within the 4T1g(4F) ground term were found at 950 and 1045 cm−1, respectively, together with higher-frequency vibronics, most of which could be assigned to combinations of these electronic transitions with transverse optic phonons. At higher Co2+ ion concentrations (e.g. x = 0.12) other absorption features were observed and these have been attributed to vibronics associated with pairs of Co2+ ions. |
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| Publication date | 1984 |
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| In | |
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| Note | Authors affiliated with NRC Physics Division at time of publication |
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| Language | English |
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| NRC number | NRC-INMS-1114 |
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| NPARC number | 8900197 |
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| Export citation | Export as RIS |
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| Report a correction | Report a correction (opens in a new tab) |
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| Record identifier | 1adf4962-f1c1-4e52-a5f1-c34ba9b71a02 |
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| Record created | 2009-04-22 |
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| Record modified | 2020-03-13 |
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