Thermal decomposition products of polyethylene

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Journal titleJournal of Polymer Science
Pages415424; # of pages: 10
Subjectpyrolysis; high density polyethylene; chromatography; free radicals; Combustion; pyrolyse; polyethylene haute densite; chromatographie; radical libre
AbstractDecomposition products of polymers have been determined by many investigators, but the results are often conflicting because of difficulties in analyzing a large number of products. A comprehensive analysis of the volatile thermal decomposition products of high-density polyethylene has been made with the latest techniques in gas chromatography. The formation of products is explained on the basis of free- radical mechanism. The predominant process in the formation of volatiles appears to be intramolecular transfer of radicals, in which isomerization by a coiling mechanism plays an important role in determining the relative quantities of each product.
Publication date
AffiliationNRC Institute for Research in Construction; National Research Council Canada
Peer reviewedYes
NRC number10212
NPARC number20375642
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Record identifier0ee355ab-e821-45fb-9dcd-8bcbace4ac6b
Record created2012-07-23
Record modified2016-05-09
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